Mass spectra of cyclic ethers formed in the low-temperature oxidation of a series of n-alkanes
Identifieur interne : 000B22 ( Main/Exploration ); précédent : 000B21; suivant : 000B23Mass spectra of cyclic ethers formed in the low-temperature oxidation of a series of n-alkanes
Auteurs : Olivier Herbinet [France] ; Sarah Bax [France] ; Pierre-Alexandre Glaude [France] ; Vincent Carré [France] ; Frédérique Battin-Leclerc [France]Source :
- Fuel (London, England) [ 0016-2361 ] ; 2011.
English descriptors
Abstract
Cyclic ethers are important intermediate species formed during the low-temperature oxidation of hydrocarbons. Along with ketones and aldehydes, they could consequently represent a significant part of the heavy oxygenated pollutants observed in the exhaust gas of engines. Apart a few of them such as ethylene oxide and tetrahydrofuran, cyclic ethers have not been much studied and very few of them are available for calibration and identification.
Electron impact mass spectra are available for very few of them, making their detection in the exhaust emissions of combustion processes very difficult. The main goal of this study was to complete the existing set of mass spectra for this class of molecules. Thus cyclic ethers have been analyzed in the exhaust gases of a jet-stirred reactor in which the low-temperature oxidation of a series of n-alkanes was taking place. Analyzes were performed by gas chromatography coupled to mass spectrometry and to MS/MS. The second goal of this study was to derive some rules for the fragmentation of cyclic ethers in electron impact mass spectrometry and allow the identification of these species when no mass spectrum is available.
Url:
DOI: 10.1016/j.fuel.2010.09.047
PubMed: 24092947
PubMed Central: 3787300
Affiliations:
- France
- Grand Est, Lorraine (région)
- Metz,Technopole, Nancy
- Centre national de la recherche scientifique, Laboratoire réactions et génie des procédés, Nancy-Université, Université de Lorraine
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Along with ketones and aldehydes, they could consequently represent a significant part of the heavy oxygenated pollutants observed in the exhaust gas of engines. Apart a few of them such as ethylene oxide and tetrahydrofuran, cyclic ethers have not been much studied and very few of them are available for calibration and identification.</p><p id="P2">Electron impact mass spectra are available for very few of them, making their detection in the exhaust emissions of combustion processes very difficult. The main goal of this study was to complete the existing set of mass spectra for this class of molecules. Thus cyclic ethers have been analyzed in the exhaust gases of a jet-stirred reactor in which the low-temperature oxidation of a series of n-alkanes was taking place. Analyzes were performed by gas chromatography coupled to mass spectrometry and to MS/MS. The second goal of this study was to derive some rules for the fragmentation of cyclic ethers in electron impact mass spectrometry and allow the identification of these species when no mass spectrum is available.</p></div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Grand Est</li><li>Lorraine (région)</li></region><settlement><li>Metz,Technopole</li><li>Nancy</li></settlement><orgName><li>Centre national de la recherche scientifique</li><li>Laboratoire réactions et génie des procédés</li><li>Nancy-Université</li><li>Université de Lorraine</li></orgName></list><tree><country name="France"><region name="Grand Est"><name sortKey="Herbinet, Olivier" sort="Herbinet, Olivier" uniqKey="Herbinet O" first="Olivier" last="Herbinet">Olivier Herbinet</name></region><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name><name sortKey="Bax, Sarah" sort="Bax, Sarah" uniqKey="Bax S" first="Sarah" last="Bax">Sarah Bax</name><name sortKey="Carre, Vincent" sort="Carre, Vincent" uniqKey="Carre V" first="Vincent" last="Carré">Vincent Carré</name><name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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